Lots of words, but no useful information. Where are you? How many people live in the house? Does anyone else in the house experience physical symptoms? How old is the house? Does the boiler run on oil or gas? Replacing a boiler because of "zoning issues" and "carbon monoxide leaking" makes absolutely no sense. IAQ assessment contractors are generally morons and IAQ testing is generally worthless. The symptoms that you describe correlate perfectly with carbon monoxide poisoning. Have you thought about getting a blood test when the symptoms are at their worst?
source https://www.inspectorsjournal.com/topic/18855-headaches-and-nausea/?do=findComment&comment=172489
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